ZeroTrace: Resource-saving activated carbon process for wastewater treatment

New adsorption materials and regeneration processes for the elimination of micropollutants in sewage treatment plants

Wuppertal-Buchenhofen sewage treatment plant

The ZeroTrace active charcoals are being used in pilot trials at the Wuppertal-Buchenhofen sewage treatment plant.

ZeroTrace active charcoals

The project produced 3 kg of ZeroTrace active charcoals with three times the electrical conductivity while maintaining the same adsorption capacity compared to conventional granulated active charcoals.

Project goals: stable composite activated carbons with increased electrical conductivity

ZeroTrace aims to establish a new active charcoal process for wastewater treatment by developing active charcoals that

  • are available in large quantities at low cost (-> industrial and muncipal applicability),
  • can be efficiently regenerated locally (-> resource conservation) and
  • remove as many types of micropollutants as possible (-> broadband effectiveness).

The main innovation is the development of stable composite active charcoals with increased electrical conductivity, which will be implemented in a new electrical regeneration process (EFSA – Electric Field Swing Adsorption) at laboratory and pilot scale.

Project benefits: sustainable wastewater treatment

About 50 million organic compounds are in circulation worldwide, of which about 5000 are classified as potentially environmentally relevant. In Germany, a densely populated country with many industrial agglomerations, wastewater and water bodies are often exceptionally highly polluted with so-called micropollutants such as pharmaceutical residues. Some of these micropollutants are difficult to break down and have a potentially toxic effect despite their very low concentration in water - usually less than one part pollutant per billion particles of water. To remove the micropollutants, sewage treatment plants in many cases use materials that can bind them. Active charcoal is one such material that binds pollutants to the surface. The water cleaned in this way leaves the sewage treatment plant; the used active charcoal is either disposed of or regenerated and reused in central treatment plants. A disadvantage is that the majority of active charcoal is extracted from hard coal - a non-renewable raw material.

The ZeroTrace consortium's solution covers the entire value added chain, starting with the development of composite active charcoal from a base material and an electrically conductive component. The modified active charcoal is assembled and tested in simple laboratory tests to determine its applicability for eliminating specific indicator micropollutants. A new regeneration process based on EFSA, which has so far only been used in gas adsorption, will be implemented and investigated on a laboratory scale for subsequent piloting. The adsorption capacity of the prioritized active charcoals will be tested at an extended laboratory scale before pilot phases with muncipal and industrial wastewater. The new activated carbon process will be evaluated taking into account socio-economic and environmental innovation drivers and barriers to ensure targeted and sustainable development.

Project partners of ZeroTrace

  • Wupperverband
  • Fraunhofer UMSICHT
  • Carbotech AC GmbH (assoziiert)
  • BAM Bundesanstalt für Materialforschung und -prüfung
  • EVERS Wassertechnik & Anthrazitveredelung GmbH & Co. KG
  • EnviroChemie GmbH
  • inter 3 Institut für Ressourcenmanagement GmbH